Total Solar Eclipse: April 8, 2024

Boron substitution represents a promising approach to stabilize carbon clathrate structures, but no thermodynamically stable substitution schemes have been identified for frameworks other than the type-VII (sodalite) structure type. To investigate the possibility for additional tetrahedral carbon-based clathrate networks, more than 5000 unique boron decoration schemes were investigated computationally for type-I and type-II carbon clathrates with a range of guest elements including Li, Na, K, Rb, Cs, Mg, Ca, Sr, and Ba. Density functional theory calculations were performed at 10 and 50 GPa, and the stability and impact of boron substitution were evaluated. The results indicate that the boron-substituted carbon clathrates are stabilized under high-pressure conditions. Full cage occupancies of intermediate-sized guest atoms (e.g., Na, Ca, and Sr) are the most favorable energetically. Clathrate stability is maximized when the boron atoms are substituted within the hexagonal rings of the large [5(12)6(2)]/[5(12)6(4)] cages. Several structures with favorable formation enthalpies <-200 meV/atom were predicted, and type-I Ca8B16C30 is on the convex hull at 50 GPa. This structure represents the first thermodynamically stable type-I clathrate identified and suggests that boron-substituted carbon clathrates may represent a large family of diamond-like framework materials with a range of structure types and guest/framework substitutions.

The approximation of real non-spherical scatterers by spheroids is used in various applications. It often requires fast massive calculations of the optical properties of spheroids. The most powerful approach to that is known to be a field expansion in terms of spheroidal wave functions, in particular, in the way suggested by Farafonov over 30 years ago. We improve the main shortcomings of such an approach. Our solution is formulated in terms of normalised spheroidal functions, and firstly for their definition given by Meixner & Schafke, which is computationally favourable and is required by the unique subroutines recently created to compute these functions. By means of T-matrix transformations we solve a long-standing major problem of Farafonov's version, namely the accuracy and time losses for one kind (TE mode) of the incident wave polarisation. Apart from this and other improvements of this solution, for the first time we relate its single particle spheroidal T-matrix to the standard spherical one which is widely employed for particle ensembles. The constructed algorithm has been extensively numerically tested. It is found to be very accurate for dielectric spheroids with the aspect ratio a/b reaching 100 and the diffraction (size) parameter xa = 2za/angstrom as large as 300, where a and b are the major and minor semi-axes, respectively, angstrom is the wavelength. The algorithm is supplied with a program interface to the free package CosTuuM to perform parallel computations of various optical properties for ensembles of spheroids with different distributions over orientation (alignment) and shape.

A miniaturized short-wavelength infrared spectrometer for use with diffuse light was created by combining a thin form factor carbon nanotube composite collimator, a linear variable filter, and an InGaAs photodiode array. The resulting spectrometer measures 3 mm × 4 mm × 14 mm and shows a significant improvement in resolution over a spectrometer without the collimator when used with diffuse light. Its small size and high throughput make it ideal for applications such as wearable optical sensing, where light from highly scattering tissue is measured. Plethysmographic measurements on the wrist were demonstrated, showing rapid data collection with diffuse light.

We present 0.'' 22-resolution Atacama Large Millimeter/submillimeter Array (ALMA) observations of CO(2-1) emission from the circumnuclear gas disk in the red nugget relic galaxy PGC 11179. The disk shows regular rotation, with projected velocities near the center of 400 km s-1. We assume the CO emission originates from a dynamically cold, thin disk and fit gas-dynamical models directly to the ALMA data. In addition, we explore systematic uncertainties by testing the impacts of various model assumptions on our results. The supermassive black hole (BH) mass (M BH) is measured to be M BH = (1.91 +/- 0.04 [1 sigma statistical] -0.51+0.11 [systematic]) x 109 M circle dot, and the H-band stellar mass-to-light ratio M/L H = 1.620 +/- 0.004 [1 sigma statistical] -0.107+0.211 [systematic] M circle dot/L circle dot. This M BH is consistent with the BH mass-stellar velocity dispersion relation but over-massive compared to the BH mass-bulge luminosity relation by a factor of 3.7. PGC 11179 is part of a sample of local compact early-type galaxies that are plausible relics of z similar to 2 red nuggets, and its behavior relative to the scaling relations echoes that of three relic galaxy BHs previously measured with stellar dynamics. These over-massive BHs could suggest that BHs gain most of their mass before their host galaxies do. However, our results could also be explained by greater intrinsic scatter at the high-mass end of the scaling relations, or by systematic differences in gas- and stellar-dynamical methods. Additional M BH measurements in the sample, including independent cross-checks between molecular gas- and stellar-dynamical methods, will advance our understanding of the co-evolution of BHs and their host galaxies.

The AGN STORM 2 campaign is a large, multiwavelength reverberation mapping project designed to trace out the structure of Mrk 817 from the inner accretion disk to the broad emission line region and out to the dusty torus. As part of this campaign, Swift performed daily monitoring of Mrk 817 for approximately 15 months, obtaining observations in X-rays and six UV/optical filters. The X-ray monitoring shows that Mrk 817 was in a significantly fainter state than in previous observations, with only a brief flare where it reached prior flux levels. The X-ray spectrum is heavily obscured. The UV/optical light curves show significant variability throughout the campaign and are well correlated with one another, but uncorrelated with the X-rays. Combining the Swift UV/optical light curves with Hubble Space Telescope UV continuum light curves, we measure interband continuum lags, tau(lambda), that increase with increasing wavelength roughly following tau(lambda) proportional to lambda 4/3, the dependence expected for a geometrically thin, optically thick, centrally illuminated disk. Modeling of the light curves reveals a period at the beginning of the campaign where the response of the continuum is suppressed compared to later in the light curve-the light curves are not simple shifted and scaled versions of each other. The interval of suppressed response corresponds to a period of high UV line and X-ray absorption, and reduced emission line variability amplitudes. We suggest that this indicates a significant contribution to the continuum from the broad-line region gas that sees an absorbed ionizing continuum.

To improve acoustical models of super heavy-lift launch vehicles, this Letter reports Space Launch System's (SLS's) overall sound power level (OAPWL) and compares it to NASA's past lunar rocket, the Saturn V. Measurements made 1.4–1.8 km from the launchpad indicate that SLS produced an OAPWL of 202.4 (⁠ 

0.5) dB re 1 pW and acoustic efficiency of about 0.33%. Adjustment of a static-fire sound power spectrum for launch conditions implies Saturn V was at least 2 dB louder than SLS with approximately twice the acoustic efficiency.